radical 4

EXCERPT:

Mechanism, synthesis, characterization, and applications of freeradical polymerization (Co)polymers prepared via free radical mechanism, together withpolyolefins, comprise the largest portion of the commodity plasticsindustry and are also used for preparation of many specialtymaterials. Handbook of Radical Polymerization provides a concisesource of information on mechanisms, synthetic techniques, andcharacterization methods and addresses future trends for polymersmade by free radical intermediates. A one-stop, at-your-fingertips source of information for students,researchers, technologists, and industrial managers, the Handbookfunctions as a single reference of the conventional andcontrolled/living radical polymerization methods. Two experteditors collect and present historical background of the technique,basic information regarding various free radical polymerizationsystems, and state-of-the-art experimental techniques andindustrial applications. Chapters written by internationallyacclaimed experts in their respective fields include: * Theory of Radical Reactions * The Kinetics of Free Radical Polymerization * Industrial Applications and Processes * Nitroxide Mediated Living Radical Polymerization * Atom Transfer Radical Polymerization * Control of Free Radical Polymerization by Chain TransferMethods * Macromolecular Engineering by Controlled RadicalPolymerization Guaranteed to have a long shelf life, the Handbook of RadicalPolymerization promises to be an indispensable resource forchemists, chemical engineers, material scientists, and graduatestudents in the field, as well as a valuable addition toindustrial, academic, and government libraries.

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Product Details :

Genre : Science
Author : Krzysztof Matyjaszewski
Publisher : John Wiley & Sons
Release : 2002-08-08
File : 920 Pages
ISBN-13 : 9780471392743
Price : FREE

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This volume from the successful Macromolecular Symposia series presents the contributions from the IUPAC-sponsored International Symposium on "Radical Polymerization: Kinetics and Mechanism", held in Il Ciocco, Italy, in September, 2006. This was the fourth within the series of so-called SML conferences, which are the major scientific forum for addressing kinetic and mechanistic aspects of free-radical polymerization and controlled radical polymerization. SML IV again marked an important step forward toward the better understanding of the kinetics and mechanism of radical polymerization, which is extremely relevant for both conventional and controlled radical polymerization and for people in academia as well as in industry. Here, top international authors, such as K. Matyjaszewski, T. P. Davis and T. Fukuda, present their latest research. The five major themes covered were: Fundamentals of free-radical polymerization, heterogeneous polymerization, controlled radical polymerization, polymer reaction engineering, and polymer characterization.

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Product Details :

Genre : Technology & Engineering
Author : Michael Buback
Publisher : John Wiley & Sons
Release : 2007-06-27
File : 270 Pages
ISBN-13 : 9783527610877
Price : FREE

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The discovery of fullerenes, species belonging to the electronodeficient polyalkenes with weakly conjugated double bonds, has opened novel opportunities for the radical chemistry. Pioneering study in this field was performed by P. J. Krusic, E. Wasserman, P. N. Keizer, J. R. Morton, and K. F. Preston (Science, 1991, 254, 1184). The fullerenyl radical adducts formed via addition of atoms or free radicals to fullerenes have no analogs in organic chemistry. In fact, radicals in which the unpaired electrons are delocalized over the surface of a sphere or ellipsoid have never been studied before. The unusual character of the fullerenyl radicals is also due to the fact that they occupy a sort of intermediate position between the planar and tetrahedral radicals. Thus, the elucidation of the characteristic features of fullerenyl radicals and their reactivity by EPR spectroscopy, and the comparison of the results with those of quantum-chemical studies are of fundamental importance. Isolation of the products from homolytic reactions of fullerenes in bulk amounts opens the door to large-scale preparation of new organic and organoelement derivatives of including biologically active ones. Radical reactions of fullerenes find wide application in the synthesis of fullere- containing polymers with valuable photophysical characteristics. Ferromagnetism of the complex of with tetra(dimethylamino)ethylene found lends impetus to a search of novel methods for preparation of biradicals one unpaired electron of those is located on the fullerene cage while the other retained by the addend.

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Product Details :

Genre : Science
Author : B.L. Tumanskii
Publisher : Springer Science & Business Media
Release : 2006-04-11
File : 193 Pages
ISBN-13 : 9780306476341
Price : FREE

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EXCERPT:

Introduction and some general concepts. -- General principles: chain reactions based on stannane chemistry. -- Further chain reactions of stannanes. -- Organo-silicon, -germanium, and -mercury hydrides. -- The Barton decarboxylation and related reactions. -- Atom and group transfer reactions. -- The persistent radical effect: non-chain processes. -- Redox processes. -- Some concluding remarks.

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Product Details :

Genre : Philosophy
Author : Samir Z. Zard
Publisher : Oxford University Press on Demand
Release : 2003
File : 256 Pages
ISBN-13 : 0198502400
Price : FREE

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Summerford describes her innovative school physical fitness and health program called PE-4-Me Radical Wellness Program, implemented at her middle school in Apple Valley, California. The program combines movement, music, authentic assessment, thematic instruction, and brain-based learning into a physical education program. Several times the role of movement and health is emphasized as a way to help students become better learners in other areas. Summerford includes seat work and activity program sheets which support the program.

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Product Details :

Genre : Education
Author : Cathie Summerford
Publisher : Human Kinetics
Release : 2000
File : 257 Pages
ISBN-13 : 0736001654
Price : FREE

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Product Details :

Genre : Technology & Engineering
Author : John A. Roth
Publisher : CRC Press
Release : 1996-09-11
File : 255 Pages
ISBN-13 : 1566764890
Price : FREE

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EXCERPT:

This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.

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Product Details :

Genre : Science
Author : Graeme Moad
Publisher : Elsevier
Release : 2006
File : 639 Pages
ISBN-13 : 0080442889
Price : FREE

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Product Details :

Genre :
Author :
Publisher :
Release : 1872
File : 523 Pages
ISBN-13 : ONB:+Z224467007
Price : FREE

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EXCERPT:

The Carotenoids book series provides an introduction to the fundamental chemistry, detailed accounts of the basic methods used in carotenoid research, and critical discussions of the biochemistry, functions and applications of carotenoids. Part 1 discusses the fundamental properties on which the biological functions and effects of carotenoids depend. Part 2 describes important natural functions of carotenoids in all kinds of living organisms.

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Product Details :

Genre : Science
Author : George Britton
Publisher : Springer Science & Business Media
Release : 2008-11-14
File : 370 Pages
ISBN-13 : 3764374993
Price : FREE

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EXCERPT:

To become fully aware of the original and radical character of his transcendental phenomenology Edmund Husserl must be located within the historical tradition of Western philosophy. Although he was not a historian of philosophy, Husserl's his torical reflections convinced him that phenomenology is the necessary culmination of a centuries-old endeavor and the solution to the contemporary crisis in European science and European humanity itself.l This teleological viewpoint re quires the commentator to consider the tradition of Western philosophy from Husserl's own perspective. Husserl maintained that the Cartesian tum to the "Cogito" represents the crucial breakthrough in the historical advance of Western thought toward philosophy as rigorous science. Hence 2 he concentrated almost exclusively on the modem era. Much has been written of Husserl's relationship to Descartes, Kant, and the neo-Kantians. His connections with Locke, Berkeley, and Hume have not been examined as closely despite his fre quent allusions to these British empiricists. Among these thinkers David Hume gained from Husserl the more extensive considera tion. Commentators have pointed out correctly that Husserl always criticized unsparingly Hume's sheer empiricistic approach to the problem of cognition. Such an approach, in Husserl's view, can only result in the "naturalization of consciousness" from which stem that "psychologism" and "sensualism" which lead Hume inevitably into the contradictory impasse of solipsism 3 and skepticism.

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Product Details :

Genre : Philosophy
Author : R.T. Murphy
Publisher : Springer Science & Business Media
Release : 2013-06-29
File : 149 Pages
ISBN-13 : 9789401743921
Price : FREE

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